Recent advances in chiral phosphine-silver(I) complex-catalyzed asymmetric reactions.
Recent advances in chiral phosphine-silver(I) complex-catalyzed asymmetric reactions.
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DOI：
10.1039/b717104h
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发表时间：
2008-02
影响因子：
4.9
通讯作者：
A. Yanagisawa;T. Arai
中科院分区：
文献类型：
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作者：
A. Yanagisawa;T. Arai
自1990年首次报道使用手性二茂铁基膦作为手性膦配体，银(I)催化活化异氰化物与醛的不对称醇醛型反应以来，各种手性膦-银(I)催化剂已被用于不对称转化。本专题文章介绍了手性膦-银(I)配合物催化的不对称反应的最新实例，例如烯丙基化、羟醛反应、曼尼希型反应、杂狄尔斯-阿尔德反应、1,3-偶极环加成和亚硝基羟醛反应。
Since the first report of silver(I)-catalyzed asymmetric aldol-type reaction of activated isocyanides with aldehydes using a chiral ferrocenylphosphine as a chiral phosphine ligand has been appeared in 1990, various chiral phosphine-silver(I) catalysts have been utilized in asymmetric transformations. This feature articles describes recent examples of chiral phosphine-silver(I) complex-catalyzed asymmetric reactions such as allylation, aldol reaction, Mannich-type reaction, hetero-Diels-Alder reaction, 1,3-dipolar cycloaddition and nitroso aldol reaction.