Planar Chiral Organosulfur Cycles
Planar Chiral Organosulfur Cycles
复制标题
平面手性有机硫循环
DOI：
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发表时间：
2009
期刊：
影响因子：
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通讯作者：
K. Tomooka
中科院分区：
文献类型：
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作者：
Kazuhiro Uehara;K. Tomooka
新合成的9元二烯丙基有机硫环已被证明具有平面手性源于其中等大小的环状结构的刚性。硫原子的氧化态显著影响它们的立体化学行为以及它们的反应性。
Newly synthesized 9-membered diallylic organosulfur cycles have proven to possess planar chirality originating from the rigidity of their medium-sized cyclic structure. The oxidation state of the sulfur atom significantly influences their stereochemical behavior as well as their reactivity.