Highly stereoselective hydroxy-directed Diels-Alder reaction
Highly stereoselective hydroxy-directed Diels-Alder reaction
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DOI：
10.1021/jo020664m
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发表时间：
2003-03-21
影响因子：
3.6
通讯作者：
Clément, R
中科院分区：
文献类型：
--
作者：
Barriault, L;Thomas, JDO;Clément, R
描述了具有仲和叔烯丙基烷氧基镁醇官能团的半环二烯与活化的亲二烯体如丙烯酸甲酯、甲基丙烯醛、丙烯醛和N-苯基马来酰亚胺的Diels-Alder反应的成功的立体控制。
The successful stereocontrol of the Diels-Alder reaction of semicyclic dienes possessing a secondary and tertiary allylic magnesium alkoxide alcohol functionality and activated dienophiles such as methyl acrylate, methacrolein, acrolein, and N-phenylmaleimide is described.