Double layer of platinum electrodes: Non-monotonic surface charging phenomena and negative double layer capacitance
Double layer of platinum electrodes: Non-monotonic surface charging phenomena and negative double layer capacitance
复制标题
双层铂电极：非单调表面充电现象和负双层电容
DOI：
10.1063/1.5010999
复制
发表时间：
2018-01-28
影响因子：
4.4
通讯作者：
Eikerling, Michael
中科院分区：
文献类型：
--
作者：
Huang, Jun;Zhou, Tao;Eikerling, Michael
在这项研究中，一个精炼的双层模型的铂电极占化学吸附的氧物种，定向界面水分子，和离子尺寸的影响在溶液中。它导致在非单调的表面充电关系和一个特殊的电容与电位曲线的最大值和可能的负值的氧化物形成的电位制度。出版社：AIP Publishing
In this study, a refined double layer model of platinum electrodes accounting for chemisorbed oxygen species, oriented interfacial water molecules, and ion size effects in solution is presented. It results in a non-monotonic surface charging relation and a peculiar capacitance vs. potential curve with a maximum and possibly negative values in the potential regime of oxide-formation. Published by AIP Publishing.