Azidoiodoiodine(1+) Hexafluoroantimonate: The First Binary Nitrogen–Iodine Cation
Azidoiodoiodine(1+) Hexafluoroantimonate: The First Binary Nitrogen–Iodine Cation
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DOI：
10.1002/anie.199213381
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发表时间：
1992-10
影响因子：
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通讯作者：
I. Tornieporth-Oetting;P. Buzek;P. Schleyer;T. Klapötke
中科院分区：
文献类型：
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作者：
I. Tornieporth-Oetting;P. Buzek;P. Schleyer;T. Klapötke
到目前为止，只描述了两种中性的二元碘氮化合物，由于非常不稳定的In键[‘]和相关的热力学不稳定性，它们都是爆炸性的：Ni，[’](或Ni.NH，[31]和我们合成类似于[NCI，]+[‘I]的“I，]’离子的尝试到目前为止还没有成功。我们在这里报道了从碘叠氮化物开始，第一个二元碘-氮阳离子的制备和表征。从叠氮银和碘新制备的碘叠氮化物(RI 1)与I，/SBF，(”[I][SBF，]“的中间产物，见参考文献[6])反应导致形成[12N3]+盐[式(A)]。
So far only two neutral binary iodine-nitrogen compounds have been described, which as a result of the very labile IN bond ['] and the associated thermodynamic instability are both explosive: NI,['](or NI,. NH,[31) and Our attempts at the synthesis of the" I,]' ion analogous to [NCI,]+['I have so far been unsuccessful.['I We report here, the preparation and characterization starting from iodoazide, of the first binary iodine-nitrogen cation. The reaction of iodoazide freshly prepared from silver azide and iodine in CFC1,(RI 1) with I,/SbF,(intermediate formation of"[I][SbF,]", see ref.[6]) leads to the formation of a [12N3]+ salt [Eq.(a)].