Three-dimensional characterization of electrodeposited lithium microstructures using synchrotron X-ray phase contrast imaging

Three-dimensional characterization of electrodeposited lithium microstructures using synchrotron X-ray phase contrast imaging
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DOI:
10.1039/c4cc03187c
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发表时间:
2015-01-01
影响因子:
4.9
通讯作者:
Lee, Peter D.
Lee, Peter D.
中科院分区:
化学2区
文献类型:
--
作者:
Eastwood, David S.;Bayley, Paul M.;Lee, Peter D.

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金属锂的电沉积是锂电池失效的主要原因。首次以亚微米分辨率表征了液体电解质中电沉积锂“苔藓”的3D微观结构。使用同步辐射X射线相衬成像,我们区分苔藓状金属锂微结构从高表面积锂盐形成的对比X射线衰减。
The electrodeposition of metallic lithium is a major cause of failure in lithium batteries. The 3D microstructure of electrodeposited lithium 'moss' in liquid electrolytes has been characterised at submicron resolution for the first time. Using synchrotron X-ray phase contrast imaging we distinguish mossy metallic lithium microstructures from high surface area lithium salt formations by their contrasting X-ray attenuation.