The synthesis of biaryl compounds by means of the diazo reaction
The synthesis of biaryl compounds by means of the diazo reaction
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DOI：
10.1021/ja01675a026
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发表时间：
1924-01-01
影响因子：
15
通讯作者：
Bachmann, WE
中科院分区：
文献类型：
--
作者：
Gomberg, M;Bachmann, WE
不同的研究人员在不同的时间观察到通过重氮反应形成联芳基化合物。这些化合物主要在以下条件下制备。重氮盐的还原。-当盐的还原仅部分地伴随着氮的释放时，除了形成烃之外，还会发生两个芳基的偶联： RN2X+ H2=
The formation of biaryl compounds through the diazo reaction has been observed at various times by different investigators. These compounds are produced principally under the followingconditions. Reduction of the Diazonium Salts.—When the reduction of the salt, accompanied by liberation of nitrogen, is only partial, then there ensues in addition to the formation of the hydrocarbon also a coupling of two aryl radicals: RN2X+ H2=