Synthesis and Characterization of Amido Pincer Complexes of Lithium and Nickel and Catalysis of the Nickel Complexes in the Kumada Cross-Coupling
Synthesis and Characterization of Amido Pincer Complexes of Lithium and Nickel and Catalysis of the Nickel Complexes in the Kumada Cross-Coupling
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锂镍酰胺钳配合物的合成、表征及镍配合物在熊田交叉偶联中的催化作用
DOI：
10.1021/om800580p
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发表时间：
2008-10
期刊：
影响因子：
2.8
通讯作者：
Wang, Zhong-Xia
中科院分区：
文献类型：
--
作者：
Sun, Kai;Wang, Li;Wang, Zhong-Xia
N-benzylidene-2-(diphenylphosphino)benzenamine(2)与Ph2PLi反应生成[Li{N{CH(Ph)PPh2}C6H4(PPh2)-2}](3)，与Ph2PCH2Li·TMEDA反应生成[Li{N{CH(Ph)-CH2PPh2}C6H4(PPh2)-2}](4)。3与(DME)NiCl2反应生成[Ni(Cl){N{CH(Ph)PP
Reaction of N-benzylidene-2-(diphenylphosphino)benzenamine (2) with Ph2PLi yielded [Li{N{CH(Ph)PPh2}C6H4(PPh2)-2}] (3), and that with Ph2PCH2Li·TMEDA generated [Li{N{CH(Ph)-CH2PPh2}C6H4(PPh2)-2}] (4). Treatment of 3 with (DME)NiCl2 gave [Ni(Cl){N{CH(Ph)PP