Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes
Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes
复制标题
DOI：
10.1039/b900976k
复制
发表时间：
2009-01-01
影响因子：
4.9
通讯作者：
Hayashi, Tamio
中科院分区：
文献类型：
--
作者：
Kawamoto, Takahiro;Hirabayashi, Sho;Hayashi, Tamio
铑催化二苯基膦烯烯的分子间不对称氢烷氧基化和氢亚砜化反应得到了乙烯醚和硫醚取代的手性烯丙基膦氧化物，收率高，对映选择性高。
The rhodium-catalyzed intermolecular asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes gave chiral allylic phosphine oxides substituted with vinyl ether and thioether moieties in high yields with high enantioselectivities.