CYCLOALKANONE PEROXIDES .2. NATURE OF PEROXIDES PRODUCED BY OXIDATION OF CYCLOPENTANOL
CYCLOALKANONE PEROXIDES .2. NATURE OF PEROXIDES PRODUCED BY OXIDATION OF CYCLOPENTANOL
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DOI：
10.1021/ja01612a011
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发表时间：
1955-01-01
影响因子：
15
通讯作者：
SCHWEITZER, CE
中科院分区：
文献类型：
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作者：
BROWN, N;ANDERSON, AW;SCHWEITZER, CE
在低温光引发体系中进行了环戊醇的液相氧气氧化反应。Milas已经描述了环状醇的光引发氧化。2在我们的研究中，在光敏安息香存在下，氧化速率明显增加。在该技术中，发现碳酸钙可提高过氧化物的稳定性;所得结果总结见表I。在石英和Pyrex牌玻璃设备中获得相同的结果。未评价环戊醇的自催化氧化，因为认为其沸点（139）太低，无法在大气压下进行令人满意的氧化。
Liquid phase oxidation of cyclopentanol by oxy-gen was carried out in a low temperature photo-initiated system. Photo-initiated oxidation of cyclic alcohols has been described by Milas. 2 In our stud-ies, a marked increase in oxidation rate was obtained by operation in the presence of the light-sensitive benzoin. Calcium carbonate was found to promote peroxide stability in this technique; results ob-tained are summarized in Table I. Identical results were obtained in quartz and in Pyrex brand glass equipment. The autocatalvzed oxidation of cyclopentanol was not evaluated as it was felt that its boiling point (139) was too low for satisfactory oxidation at atmospheric pressure.