Nanofabrication and characterization of ZnO nanorod arrays and branched microrods by aqueous solution route and rapid thermal processing
Nanofabrication and characterization of ZnO nanorod arrays and branched microrods by aqueous solution route and rapid thermal processing
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DOI：
10.1016/j.mseb.2007.10.004
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发表时间：
2007-12-20
期刊：
影响因子：
--
通讯作者：
Heinrich, Helge
中科院分区：
文献类型：
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作者：
Lupan, Oleg;Chow, Lee;Heinrich, Helge
本文提出了一种廉价、快速的一维(1D)氧化锌纳米棒阵列和分支二维(2D)、三维(3D)纳米结构的制备方法。我们的合成技术包括使用水溶液路线和生长后快速热退火。它允许在不使用模板或种子的情况下快速、可控地生长1D-杆、2D-十字和3D-四脚的氧化锌纳米棒阵列。得到的氧化锌纳米棒均匀分布在硅衬底表面，单个或分枝的纳米/微米棒可以很容易地转移到其他衬底上。浓度、温度和时间、衬底类型和反应器设计等工艺参数是形成具有细小直径和可转移纳米结构的纳米棒阵列的关键。用X射线衍射仪、扫描电子显微镜、X射线光电子能谱、透射电子显微镜和显微拉曼光谱对样品进行了表征。(C)2007 Elsevier B.V.保留所有权利。
This paper presents an inexpensive and fast fabrication method for one-dimensional (1D) ZnO nanorod arrays and branched two-dimensional (2D), three-dimensional (3D) - nanoarchitectures. Our synthesis technique includes the use of an aqueous solution route and post-growth rapid thermal annealing. It permits rapid and controlled growth of ZnO nanorod arrays of 1D - rods, 2D - crosses, and 3D - tetrapods without the use of templates or seeds. The obtained ZnO nanorods are uniformly distributed on the surface of Si substrates and individual or branched nano/microrods can be easily transferred to other substrates. Process parameters such as concentration, temperature and time, type of substrate and the reactor design are critical for the formation of nanorod arrays with thin diameter and transferable nanoarchitectures. X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, transmission electron microscopy and Micro-Raman spectroscopy have been used to characterize the samples. (C) 2007 Elsevier B.V. All rights reserved.