Synthesis and isomerization of imino-fused N-confused porphyrin.
Synthesis and isomerization of imino-fused N-confused porphyrin.
复制标题
DOI：
10.1021/ol0703534
复制
发表时间：
2007-04
期刊：
影响因子：
5.2
通讯作者：
Norimasa Kashiwagi;T. Akeda;Tatsuki Morimoto;Tomoya Ishizuka;H. Furuta
中科院分区：
文献类型：
--
作者：
Norimasa Kashiwagi;T. Akeda;Tatsuki Morimoto;Tomoya Ishizuka;H. Furuta
[反应：见正文]由21-氨基取代的NCP与芳醛缩合反应合成了一系列可相互转化的亚氨基稠合N-混杂卟啉(IF-NCPs)，其结构经X-射线单晶分析表征。
[reaction: see text] A set of mutually interconvertable inner-bridged-type porphyrinoids, imino-fused N-confused porphyrins (IF-NCPs), which possess a [5.7.5] tricyclic ring in the core, were synthesized from a condensation reaction of 21-amino-substituted NCP and an arylaldehyde, and the structures were characterized by X-ray single-crystal analysis.