Tuning the structure and properties of a multiferroic metal-organic-framework via growing under high magnetic fields.

Tuning the structure and properties of a multiferroic metal-organic-framework via growing under high magnetic fields.
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通过在高磁场下生长来调节多铁性金属有机框架的结构和性能

DOI:
10.1039/c8ra00799c
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发表时间:
2018-04-11
期刊:
影响因子:
3.9
通讯作者:
Chen, Qianwang
Chen, Qianwang
中科院分区:
化学3区
文献类型:
--
作者:
Hu, Lin;Wang, Zhe;Wang, Hui;Qu, Zhe;Chen, Qianwang

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高磁场诱导合成的多铁性金属有机骨架化合物[(CH3)2NH2][Mn(HCOO)3]的结构和性质已被证明是可调的。在90 kOe下获得的晶体表现出较低的铁电极化值和降低的磁化率,与没有场的情况下获得的晶体相比,这归因于由高磁场引起的结构变化。高磁场诱导合成的多铁性金属有机骨架化合物[(CH3)2NH2][Mn(HCOO)3]的结构和性质已被证明是可调的。
High magnetic field-induced synthesis has been demonstrated to tune the structure and properties of the multiferroic metal–organic framework [(CH3)2NH2][Mn(HCOO)3]. The crystals obtained under 90 kOe exhibit a lower ferroelectric polarization value and reduced magnetic susceptibility, compared to crystals obtained without a field, which is attributed to structural changes induced by the high magnetic field. High magnetic field-induced synthesis has been demonstrated to tune the structure and properties of the multiferroic metal–organic framework [(CH3)2NH2][Mn(HCOO)3].
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