Functionalized nanodiamonds part 3: thiolation of tertiary/bridgehead alcohols.
Functionalized nanodiamonds part 3: thiolation of tertiary/bridgehead alcohols.
复制标题
功能化纳米金刚石第 3 部分：叔醇/桥头醇的硫醇化。
DOI：
10.1021/ol053136g
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发表时间：
2006
期刊：
影响因子：
5.2
通讯作者：
P. Schreiner
中科院分区：
文献类型：
--
作者：
B. Tkachenko;N. Fokina;Lesya V. Chernish;J. Dahl;Shenggao Liu;R. Carlson;A. Fokin;P. Schreiner
[反应：见正文]在氢溴酸和醋酸存在下，用硫脲处理无环和多环的叔基单羟基和二羟基烃衍生物是一种方便的一步法，可得到相应的叔硫醇和二硫醇。该方法被用于制备金刚烷、金刚烷、[121]十四烷和其他潜在的纳米电子材料的金刚烷类硫醇。
[reaction: see text] Treatment of acyclic as well as polycyclic tertiary mono- and dihydroxy hydrocarbon derivatives with thiourea in the presence of hydrobromic and acetic acid represents a convenient one-step route to the respective tertiary thiols and dithiols. This procedure was used for the preparation of diamondoid thiols of diamantane, triamantane, [121]tetramantane, and others that are prospective nanoelectronic materials.