NiS2 nanosheets array grown on carbon cloth as an efficient 3D hydrogen evolution cathode

NiS2 nanosheets array grown on carbon cloth as an efficient 3D hydrogen evolution cathode
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DOI:
10.1016/j.electacta.2014.12.043
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发表时间:
2015-01-20
影响因子:
6.6
通讯作者:
Sun, Xuping
Sun, Xuping
中科院分区:
材料科学2区
文献类型:
--
作者:
Tang, Chun;Pu, Zonghua;Sun, Xuping

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本文首次将NiS2NA/CC的前驱体Ni(OH)(2)Na/CC硫化,在碳布上制备了NiS2NA/CC纳米片阵列。作为三维析氢阴极,NiS2NA/CC电极在中性溶液中表现出良好的催化活性和稳定性。需要193 mV和243 mV的过电位才能提供2 mA/cm(2)和10 mA/cm(2)的电流密度。这种电极在碱性溶液中也能有效工作。(C)2014爱思唯尔有限公司。保留所有权利。
In this paper, we demonstrate the first preparation of NiS2 nanosheets array on carbon cloth (NiS2 NA/CC) via sulfidization of its Ni(OH)(2) NA/CC precursor. As a 3D hydrogen evolution cathode, the NiS2 NA/CC electrode shows excellent catalytic activity and stability in neutral solutions. It needs overpotentials of 193 and 243 mV to afford current densities of 2 and 10 mA/cm(2), respectively. This electrode also works efficiently in basic solutions. (C) 2014 Elsevier Ltd. All rights reserved.