2-[(1S,3S)-3-Acetyl-2,2-dimethyl-cyclo-butyl]-N-(m-tol-yl)acetamide.
2-[(1S,3S)-3-Acetyl-2,2-dimethyl-cyclo-butyl]-N-(m-tol-yl)acetamide.
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2-[(1S,3S)-3-乙酰基-2,2-二甲基环丁基]-N-(间甲苯基)乙酰胺。
DOI：
10.1107/s160053680706641x
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发表时间：
2007
期刊：
影响因子：
--
通讯作者：
Shang,Shi-Bin
中科院分区：
文献类型：
--
作者：
Yin,Yan-Bai;Song,Zhan-Qian;Wang,Zong-De;Shang,Shi-Bin
标题化合物 C17H23NO2 含有两个手性中心，由 2-(3-乙酰基-2,2-二甲基环丁基)乙酸和间甲苯胺合成。环丁烷环不是平的，而是弯曲的，好像从二甲基取代的C原子折叠到未取代的C原子上，二面角为25.9°。晶体结构通过 N—H⋯O 和 C—H⋯O 氢键相互作用稳定。
The title compound, C17H23NO2, contains two chiral centres and was synthesized from 2-(3-acetyl-2,2-dimethylcyclobutyl)acetic acid and m-toluidine. The cyclobutane ring is not flat but flexed as though folded from the dimethyl-substituted C atom to the unsubstituted C atom, with a dihedral angle of 25.9°. The crystal structure is stabilized by N—H⋯O and C—H⋯O hydrogen-bonding interactions.