Simple primary anilines as iminium catalysts for the epoxidation of α-substituted acroleins
Simple primary anilines as iminium catalysts for the epoxidation of α-substituted acroleins
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DOI：
10.1002/adsc.200700048
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发表时间：
2007-04-01
影响因子：
5.4
通讯作者：
Clarke, Melanie-Rose
中科院分区：
文献类型：
--
作者：
Erkkila, Anniina;Pihko, Petri M.;Clarke, Melanie-Rose
简单的邻位烷基化苯胺已被证明是用于α-取代丙烯醛环氧化反应的优异的亚胺催化剂。一系列不同的α-取代丙烯醛使环氧化物产物具有良好至优异的产率和良好的化学选择性。
Simple ortho-alkylated anilines have been shown to be excellent iminium catalysts for the epoxidation reaction of alpha-substituted acroleins. A range of different alpha-substituted acroleins give the epoxide products in good to excellent yields and good chemoselectivity.