Synthesis and Dynamic Structures of a Hybrid Nanohoop Molecule Composed of Anthanthrenylene and Phenylene Panels
Synthesis and Dynamic Structures of a Hybrid Nanohoop Molecule Composed of Anthanthrenylene and Phenylene Panels
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DOI：
10.1246/cl.150801
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发表时间：
2015-11-05
影响因子：
1.6
通讯作者：
Isobe, Hiroyuki
中科院分区：
文献类型：
--
作者：
Sarkar, Parantap;Sato, Sota;Isobe, Hiroyuki
合成了一种由蒽撑和苯撑组成的杂化纳米环分子。通过NMR光谱的结构分析揭示了亚芳基面板在溶液中的同步动力学。理论计算进一步阐明了参与动力学的分子结构，并显示了相邻亚芳基面板的相关旋转。
A hybrid nanohoop molecule composed of anthanthrenylene and phenylene panels was synthesized. Structural analysis by NMR spectroscopy revealed the synchronous dynamics of the arylene panels in solution. Theoretical calculations further clarified the molecular structures involved in the dynamics and showed correlated rotations of neighboring arylene panels.