AlMe3-promoted oxidative cyclization of η2-alkene and η2-ketone on nickel(0).: Observation of intermediate in methyl transfer process
AlMe3-promoted oxidative cyclization of η2-alkene and η2-ketone on nickel(0).: Observation of intermediate in methyl transfer process
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DOI：
10.1021/ja0542486
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发表时间：
2005-09-21
影响因子：
15
通讯作者：
Kurosawa, H
中科院分区：
文献类型：
--
作者：
Ogoshi, S;Ueta, M;Kurosawa, H
AlMe3能促进η-2-烯烃和η-2-酮在镍(0)上的氧化环化反应，得到一个具有桥联甲基的镍−铝双核配合物，它可能是镍催化邻烯丙基苯乙酮或邻烯丙基二苯甲酮环异构化反应的中间体。
AlMe3can promote the oxidative cyclization of η2-alkene and η2-ketone on nickel(0) to give an intriguing nickel−aluminum dinuclear complex having a bridging methyl group, which might be an intermediate for the nickel-catalyzed cycloisomerization ofo-allylacetophenone oro-allylbenzophenone.