Design and control of LCST behaviour of zwitterion/aqueous Broensted acid mixtures
Design and control of LCST behaviour of zwitterion/aqueous Broensted acid mixtures
复制标题
两性离子/布朗斯台德酸水溶液混合物的 LCST 行为的设计和控制
DOI：
10.1002/chem.201683561
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发表时间：
2016
期刊：
影响因子：
--
通讯作者：
and H. Ohno
中科院分区：
文献类型：
--
作者：
Y. Mieno;Y. Kohno;S. Saita;and H. Ohno
两性离子Brnsted酸混合物一种氨型两性离子，在混合等摩尔量的三氟甲磺酸(一种典型的Brnsted酸)后，与水表现出较低的临界溶液温度类型的相行为。这种类型的双水相体系考虑到它们的性质组合，如热响应性和酸性官能度，可以提供不同的应用。潜在的应用包括新型催化反应/产物分离系统。有关更多细节，请参见H.Ohno等人的通信。在12262页以下。
Zwitterion Brønsted Acid Mixture An ammonium-type zwitterion was designed to show a lower critical solution temperature-type phase behavior with water after mixing an equimolar amount of trifluoromethanesulfonic acid, a typical Brønsted acid. This type of aqueous two-phase system affords diverse applications upon considering their combination of properties, such as thermoresponsiveness and acid functionality. Potential applications include novel catalytic reaction/product separation systems. For more details, see the Communication by H. Ohno et al. on page 12262 ff.