N‐Allylideneamines Derived from Acrolein: Synthesis and Use as Acceptors of Two Nucleophiles

N‐Allylideneamines Derived from Acrolein: Synthesis and Use as Acceptors of Two Nucleophiles
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丙烯醛衍生的 N-烯丙胺:合成及其作为两种亲核试剂受体的用途

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发表时间:
2009
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通讯作者:
M. Shimizu
M. Shimizu
中科院分区:
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作者:
Isao Mizota;Yuri Matsuda;I. Hachiya;M. Shimizu

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Two practical methods have been developed for the preparation of N-allylideneamines 1b,c. One involves the isomerization of propargylamines and the other the dehydration of acrolein. N-Allylideneamines 1b,c thus prepared were used as efficient substrates for 1,4- and 1,2-double nucleophilic addition reactions. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)