The fabrication of polyfluorene and polycarbazole-based photovoltaic devices using an air-stable process route
The fabrication of polyfluorene and polycarbazole-based photovoltaic devices using an air-stable process route
复制标题
DOI：
10.1063/1.4902990
复制
发表时间：
2014-12-01
影响因子：
4
通讯作者：
Lidzey, D. G.
中科院分区：
文献类型：
--
作者：
Bovill, E.;Yi, H.;Lidzey, D. G.
我们报告了一项基于聚合物制造的比较研究：包含咔唑、芴和基于PTB的共聚物的富勒烯光伏（PV）器件。我们已经探索了这样的设备的效率和性能时，活性聚合物：富勒烯层是通过旋转铸造在氮气或环境条件下沉积。我们发现，基于咔唑和芴基材料的光伏器件在空气和氮气下处理时具有非常相似的功率转换效率，其他光漂白测量表明，这种材料具有相对增强的光稳定性。然而，基于PTB共聚物的器件在空气中加工时效率降低。(C)2014 AIP出版有限责任公司。
We report a comparative study based on the fabrication of polymer: fullerene photovoltaic (PV) devices incorporating carbazole, fluorene, and a PTB based co-polymer. We have explored the efficiency and performance of such devices when the active polymer: fullerene layer is deposited by spin-casting either under nitrogen or ambient conditions. We show that PV devices based on carbazole and fluorene based materials have very similar power conversion efficiencies when processed under both air and nitrogen, with other photobleaching measurements suggesting that such materials have comparatively enhanced photostability. Devices based on the PTB co-polymer, however, have reduced efficiency when processed in air. (C) 2014 AIP Publishing LLC.