Improved synthetic route to 11, 11, 12, 12-tetracyanonaphtho-2,6-quinodimethan
Improved synthetic route to 11, 11, 12, 12-tetracyanonaphtho-2,6-quinodimethan
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11,11,12,12-四氰基萘-2,6-醌二甲烷的改进合成路线
DOI：
10.1021/jo00922a035
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发表时间：
1974
影响因子：
3.6
通讯作者：
A. Garito
中科院分区：
文献类型：
--
作者：
D. Sandman;A. Garito
(TNAP，1)是7，7，8，8-四氰基喹二甲烷(TCNQ，2)的扩展共轭类似物，TCNQ，2是最高电导率有机固体的受体摩尔数。事实上，在电荷转移盐中观察到了巨大的电导率极大值，归因于高温(60K)下的超导波动，其中施主是四硫富瓦烯(TTf，3)，受主是2.3
(TNAP, 1) is an extended conjugated analog of 7, 7, 8, 8-tetracyanoquinodimethan (TCNQ, 2), the acceptor mole-cule on which the highest conductivity organic solids are based. Indeed, giant conductivity maxima, attributed to superconducting fluctuations at high (60 K) temperatures, have been observed in charge-transfer salts where the donor is based on tetrathiafulvalene (TTF, 3) and the acceptor is 2.3