DIAZOTATIVE DEAMINOSILYLATION OF BETA-AMINO SILANES
DIAZOTATIVE DEAMINOSILYLATION OF BETA-AMINO SILANES
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DOI：
10.1021/jo00301a053
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发表时间：
1990-07-06
影响因子：
3.6
通讯作者：
CUNICO, RF
中科院分区：
文献类型：
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作者：
CUNICO, RF
X= OH，OY（酯，醚），-，卤素很少见。事实上，早期的这些工作令人沮丧，因为 Sommer 和同事发现，与 (3-羟乙基) 硅烷的行为完全相反，用浓硫酸加热 (d-氨基乙基) 三甲基硅烷会导致硅-甲基裂解而不是去消除 (eq 2)。 2 据我们所知，没有其他关于
X= OH, OY (ester, ether),-, halogen is rare. Indeed, early work along these lines was discouraging, as Sommer and co-workers found that, in total contrast to the behavior of (/3-hydroxyethyl) silanes, heating (d-aminoethyl) trimethylsilane with concentrated sulfuric acid caused silicon-methyl cleavage instead of d-elimination (eq 2). 2 We are aware of no other report concerning