Polar electro-optic switching in droplets of an achiral nematic liquid crystal

Polar electro-optic switching in droplets of an achiral nematic liquid crystal
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DOI:
10.1080/026782999203896
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发表时间:
1999-10
期刊:
影响因子:
2.2
通讯作者:
P. Rudquist;Eva D Korblova;D. Walba;R. Shao;N. Clark;J. Maclennan
P. Rudquist;Eva D Korblova;D. Walba;R. Shao;N. Clark;J. Maclennan
中科院分区:
化学3区
文献类型:
--
作者:
P. Rudquist;Eva D Korblova;D. Walba;R. Shao;N. Clark;J. Maclennan

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A polar electro-optic response is observed in droplets of an achiral nematic liquid crystal in coexistence with the isotropic phase. Between crossed polarizers each pancake-shaped droplet shows extinction brushes in the form of a centred cross aligned with the polarizer axes. An applied electric field E induces a rotation of the crosses about the field direction, with about half the droplets switching clockwise and the other half anticlockwise. The sense of rotation in each droplet changes when E is reversed. We propose that a twisted bipolar director structure is stabilized in the droplets by a relatively large splay elastic constant and tangential boundary conditions. The molecules twist along the diameter of the droplets, perpendicular to the applied field, which results in a linear rotation of the director by the inverse flexoelectric effect. Since the molecules are achiral, the handedness of the twist, and hence the sense of the switching, in any droplet is arbitrary.