Effect of barium loading on CuOx-CeO2 catalysts: NOx storage capacity, NO oxidation ability and soot oxidation activity
Effect of barium loading on CuOx-CeO2 catalysts: NOx storage capacity, NO oxidation ability and soot oxidation activity
复制标题
钡负载量对 CuOx-CeO2 催化剂的影响：NOx 存储能力、NO 氧化能力和烟灰氧化活性
DOI：
10.1016/j.cattod.2011.03.002
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发表时间：
2011-10-25
期刊：
影响因子：
5.3
通讯作者：
Weng, Duan
中科院分区：
文献类型：
--
作者：
Lin, Fan;Wu, Xiaodong;Weng, Duan
A series of Ba-Cu-Ce catalysts were prepared by loading different amounts of Ba(Ac)(2) on the sol-gel-synthesized CuOx-CeO2 mixed oxides. The activities of the catalysts for soot oxidation were evaluated in 1000 ppm NO/10% O-2/N-2 under loose contact conditions. The catalysts were characterized by XRD, BET, H2-TPR, in situ-DRIFTS and NO-TPO measurements. When Ba loading is between 6 and 10 mol.% of Cu + Ce, the catalysts exhibit an onset temperature (T-i) as low as 376 degrees C. NO is oxidized at Cux+ and Cex+ sites and then stored on the adjacent Ba species in form of barium nitrate. Ba(NO3)(3) begins to decompose, releasing abundant NO2 at around 370 degrees C under the driving of soot as the reductant. The nitrate-derived NO2 and the NO-derived NO2 initiate the soot combustion over the Ba-modified catalysts with a significantly lowered T-i. The ternary catalysts lose their NOx storage capacity after hydrothermally aged at 800 degrees C for 10 h due to the formation of BaCeO3. However, Ba restrains the sintering of (Cu,Ce)O-x, resulting in relatively more favorable redox properties and thus higher activity for NO oxidation. The barium-modified catalysts show lower onset temperatures (470-480 degrees C) of soot oxidation than pure CuCe (509 degrees C) after aging. (C) 2011 Elsevier B.V. All rights reserved.
