BODIPY photocatalyzed oxidation of thioanisole under visible light
BODIPY photocatalyzed oxidation of thioanisole under visible light
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DOI：
10.1016/j.catcom.2011.09.007
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发表时间：
2011-11-30
影响因子：
3.7
通讯作者：
Jing, Xiabin
中科院分区：
文献类型：
--
作者：
Li, Wenliang;Xie, Zhigang;Jing, Xiabin
4，4-二氟-4-硼杂-3a，4a-diaza-s-indacene（BODIPY）染料是一类具有优异的热稳定性、光稳定性、高荧光量子产率和良好溶解性的有机染料。合成了四种BODIPY染料，并用于研究苯硫醚在可见光下的氧化反应。BODIPY染料显示出与金属络合物（如Ru（bpy）（3）（2+））相当的高活性光催化剂。这项工作突出了使用BODIPY作为光催化剂用于许多重要有机转化的潜力。(C)2011 Elsevier B. V.保留所有权利。
4,4-Difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dyes are organic dyes which have excellent thermal and photochemical stability, high fluorescence quantum yield and good solubility. Four BODIPY dyes were made and used to investigate the oxidation of thioanisole under visible light. BODIPY dyes were shown to be highly active photocatalysts which are comparable to the metal complex, like Ru(bpy)(3)(2+). This work highlights the potential of using BODIPY as photocatalysts for a number of important organic transformations. (C) 2011 Elsevier B.V. All rights reserved.