Effects of Capping Electrode on Ferroelectric Properties of Hf0.5Zr0.5O2 Thin Films

Effects of Capping Electrode on Ferroelectric Properties of Hf0.5Zr0.5O2 Thin Films
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盖电极对Hf0.5Zr0.5O2薄膜铁电性能的影响

DOI:
10.1109/led.2018.2846570
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发表时间:
2018-08-01
影响因子:
4.9
通讯作者:
Liu, Ming
Liu, Ming
中科院分区:
工程技术2区
文献类型:
--
作者:
Cao, Rongrong;Wang, Yan;Liu, Ming

文献摘要

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本文系统地研究了顶部电极(TEs)对Hf-0.5 Zr-0.5 O-2 (HZO)薄膜铁电性能的影响。随着热膨胀系数(α)的降低,te的改变增加了HZO薄膜的残余极化(P-r)。α = 4.5 × 10(-6)/K的W TE的2P(r)值最大,为38.72亩C/cm(2), α = 14.2 × 10(-6)/K的Au TE的2P(r)值仅为22.83亩C/cm(2)。同时,矫顽力场(E-c)沿电场轴发生偏移,偏移量与TE和TiN底电极(be)的功函数(WFs)差有关。当TE的wf (Pt、Pd、Au/W、Al、Ta)大于/小于TiN BE时,E-c向负/正方向偏移。这封信提供了一种有效的方法来调制基于hfo2的器件性能,以满足实际应用中的不同要求。
In this letter, effects of top electrodes (TEs) on ferroelectric properties of Hf-0.5 Zr-0.5 O-2 (HZO) thin films are examined systematically. The remnant polarization (P-r) of HZO thin films increases by altering TEs with lower thermal expansions coefficient (alpha). The largest 2P(r) value of 38.72 mu C/cm(2) is observed for W TE with alpha = 4.5 x 10(-6)/K, while the 2P(r) value is only 22.83 mu C/cm(2) for Au TE with alpha = 14.2x10(-6)/K. Meanwhile, coercivefield (E-c) shifts along the electric field axis and the offset is found to be dependent on the difference of workfunctions (WFs) between TE and TiN bottom electrode (BE). E-c shifts toward negative/positive direction, when theWF of TE is larger/smaller (Pt, Pd, Au/W, Al, Ta) than TiN BE. This letter provides an effective way to modulate HfO2-based device performance for different requirements in actual application.