Photocatalytic reduction of carbon tetrachloride by natural sphalerite under visible light irradiation

Photocatalytic reduction of carbon tetrachloride by natural sphalerite under visible light irradiation
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可见光照射下天然闪锌矿光催化还原四氯化碳

DOI:
10.1016/j.solmat.2011.02.020
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发表时间:
2011-07
影响因子:
6.9
通讯作者:
Po-Keung Wong
Po-Keung Wong
中科院分区:
材料科学2区
文献类型:
--
作者:
Yan Li;Xinge Yang;Anhuai Lu;Yunhua Yan;Changqiu Wang;Po-Keung Wong

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The photoreductive degradation of carbon tetrachloride (CT) in natural sphalerite ((Zn, Fe)S mineral) suspensions irradiated by visible light (VL) is studied in this paper. 92% of CT is degraded in N,N-dimethylformamide (DMF) organic solvent system after 8h of VL irradiation. The effects of light source, sphalerite dosage, electron donors, dissolved oxygen and CT initial concentration on CT photocatalytic degradation efficiency are discussed. The degradation products are analyzed by gas chromatography–mass spectrometry (GC–MS), and the photocatalytic degradation mechanism is then proposed.
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期刊: The journal of physical chemistry. A
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