Enhanced electro-optic coefficient of nonlinear optical polymer using liquid contact poling

Enhanced electro-optic coefficient of nonlinear optical polymer using liquid contact poling
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使用液体接触极化增强非线性光学聚合物的电光系数

DOI:
10.1063/1.118333
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发表时间:
1997
影响因子:
4
通讯作者:
Ray T. Chen
Ray T. Chen
中科院分区:
物理与天体物理2区
文献类型:
--
作者:
Huajun Tang;J. Taboada;G. Cao;Liqiang Li;Ray T. Chen

文献摘要

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电光(EO)聚合物膜的电光系数r33的值取决于在电极化过程之后实现的偏振密度。本文报道了一种高温液体接触极化方法,在LD-3EO聚合物薄膜中获得了高达250 V/μm的极化电场,且表面损伤较小。在633 nm处测得的r33值为18 pm/V,比先前报道的数据高40°/V。这样的高极化场和因此更大的r33值通过接触极化或电晕极化都不能实现。
The value of electro-optic coefficient r33 of an electro-optic (EO) polymer film depends on the polarization density achieved after the electric poling process. In this letter, we report a high temperature liquid contact poling method which provides a poling field as high as 250 V/μm in LD-3 EO polymer film with less surface damages. The r33 value was measured to be 18 pm/V at 633 nm which is 40°/V higher than the previous reported datum. Such a high poling field and therefore larger r33 value are not achievable through either contact poling or corona poling.