Porphyrins with β,β'-fused five-membered rings
Porphyrins with β,β'-fused five-membered rings
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DOI：
10.1142/s1088424605000873
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发表时间：
2005-11
影响因子：
1.5
通讯作者：
Kevin M Smith;S. H. Lee;M. Vicente
中科院分区：
文献类型：
--
作者：
Kevin M Smith;S. H. Lee;M. Vicente
综述了近几年来有关含稠合五元环的卟啉体系的研究，包括吡咯并[3，4-b]卟啉和稠合金属茂卟啉。讨论了吡咯卟啉之间的Diels-Alder环加成反应，得到苯并卟啉。然后讨论了双磺基卟啉的单异构体和两个区域异构体(adj-和opp-)的合成，并概述了它们与乙酰二甲酸二甲酯等亲二烯化合物的反应。
Recent studies involving porphyrin systems bearing fused five-membered rings are reviewed, these including pyrrolo[3,4-b]porphyrins and fused metallocenoporphyrins. Diels-Alder cycloadditions between pyrroloporphyrins, to give benzoporphyrins, are discussed. The syntheses of mono-, and the two regioisomers (adj- and opp-) of bis-sulfolenoporphyrins are then discussed and their reactions with dienophiles such as dimethyl acetylenedicarboxylate are outlined.