Visible light-induced magnetization change of the cyano-bridged 3d-4f heterobimetallic

Visible light-induced magnetization change of the cyano-bridged 3d-4f heterobimetallic
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DOI:
10.1016/j.jssc.2004.06.015
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发表时间:
2004-10
影响因子:
3.3
通讯作者:
Guangming Li;O. Sato;T. Akitsu;Y. Einaga
Guangming Li;O. Sato;T. Akitsu;Y. Einaga
中科院分区:
化学3区
文献类型:
--
作者:
Guangming Li;O. Sato;T. Akitsu;Y. Einaga

文献摘要

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研究了3d-4f异质金属[Nd(DMF)4(H2O)3(μ-NC)Co(CN)5]·H2O (DMF=N,N-二甲基甲酰胺)在可见光诱导下的磁化变化。配合物的χMT与T的对比图显示,在5-40K温度范围内,可见光照射后的χMT值比照射前提高了约25%。
A visible light-induced magnetization change of the 3d–4f heterometallic, [Nd(DMF)4(H2O)3(μ-NC)Co(CN)5]·H2O (DMF=N,N-dimethylformamide), is observed and described. The plots of χMT versus T of the complex showed that the χMT values, after visible light illumination, were enhanced by about 25% as compared to before irradiation in the temperature range of 5–40K.