Enzyme promiscuity:: first protein-catalyzed Morita-Baylis-Hillman reaction
Enzyme promiscuity:: first protein-catalyzed Morita-Baylis-Hillman reaction
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DOI：
10.1016/j.tetlet.2007.01.063
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发表时间：
2007-03-05
影响因子：
1.8
通讯作者：
Carballeira, Jose Daniel
中科院分区：
文献类型：
--
作者：
Reetz, Manfred T.;Mondiere, Regis;Carballeira, Jose Daniel
环己烯酮和对硝基苯甲醛的Morita-Baylis-Hillman反应由载体蛋白如血清白蛋白或酶如某些脂肪酶催化，观察到高达35%的转化率和高达19%的对映选择性。(c)2007爱思唯尔有限公司保留所有权利。
The Morita-Baylis-Hillman reaction of cyclohexenone and p-nitro benzaldehyde is catalyzed by carrier proteins such as serum albumins or enzymes such as certain lipases, conversion of up to 35% and enantio selectivities of up to 19% being observed. (c) 2007 Elsevier Ltd. All rights reserved.