Use of sterically hindered sensitizers for improved photoinduced electron-transfer reactions
Use of sterically hindered sensitizers for improved photoinduced electron-transfer reactions
复制标题
使用位阻敏化剂改善光诱导电子转移反应
DOI：
10.1021/ja00026a034
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发表时间：
1991
影响因子：
15
通讯作者：
S. A. D. Silva
中科院分区：
文献类型：
--
作者：
P. G. Gassman;S. A. D. Silva
增加产物产率和量子产率可以通过使用空间位阻光敏剂来实现。以5-甲基-4-己烯酸的反马氏内酯化反应为模型反应，对一系列光敏剂进行了评价。
Increasing both product yields and quantum yields can be accomplished throuth the use of sterically encumbered photosensitizers. The anti-Markovnikov lactonization of 5-methyl-4-hexenoic acid, a photoinduced SET reaction was chosen as the model reaction for the evaluation of a series of sensitizers.