Towards the development of a hydrogen battery

Towards the development of a hydrogen battery
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DOI:
10.1039/c2ee22043a
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发表时间:
2012-10-01
影响因子:
32.5
通讯作者:
Beller, Matthias
Beller, Matthias
中科院分区:
材料科学1区
文献类型:
--
作者:
Boddien, Albert;Federsel, Christopher;Beller, Matthias

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一种新的钌催化的二氧化碳氢化反应以前所未有的高甲酸与胺的比率(AAR为2.69)进行,这导致能量含量的提高。所提出的催化剂体系允许可逆的快速氢加载(甚至在RT下)和前所未有的卸载(TON,对于800 000的H-2释放)。
A novel Ru-catalyzed hydrogenation of carbon dioxide proceeds with an unprecedented high formic acid to amine ratio (AAR of 2.69), which results in an improved energy content. The presented catalyst system allows for reversible fast hydrogen loading (even at RT) and unprecedented unloading (TON for H-2 liberation of 800 000).