Chiral and achiral crystal structures

Chiral and achiral crystal structures
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DOI:
10.1002/hlca.200390109
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发表时间:
2003-01-01
影响因子:
1.8
通讯作者:
Flack, HD
Flack, HD
中科院分区:
化学4区
文献类型:
--
作者:
Flack, HD

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本文对晶体结构及其组分中手性的概念、分类、表征和命名以及手性的缺失进行了广泛的研究和分析。定向晶体结构分类。研究了分子晶体结构存在的手性规则,并强调了与分割和潜在对称性的关系。介绍了手性和相关术语的命名,以及手性与旋光性的关系。欧几里德规范化的用途和局限性进行治疗。其中包括一个经过改进的术语表。
An extensive study and analysis of the concepts, classification, presentation, and nomenclature of chirality and lack of chirality in crystal structures and their constituents is presented. Oriented crystal structures are classified. The chirality rules for existence of molecular crystal structures are examined and the relation to segmentation and latent symmetry highlighted. The nomenclature of chirality and related terms, and the relationship of chirality to optical activity is covered. The uses and limitations of the Euclidean normalizer are treated. An improved glossary of terms is included.