Activation and copolymerization of CO2 by macromolecule-metal complexes

Activation and copolymerization of CO2 by macromolecule-metal complexes
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DOI:
10.1002/masy.19920590108
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发表时间:
1992-06
影响因子:
--
通讯作者:
Li-Ban Chen
Li-Ban Chen
中科院分区:
--
文献类型:
--
作者:
Li-Ban Chen

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使用由合适的螯合聚合物、合适的双金属组合组成的催化剂,并通过适当的步骤制备,可以促进CO2和相关共聚单体的活化。用这种方法高产率地合成了脂肪族聚碳酸酯、聚碳酸酯-聚氨酯、饱和和不饱和聚碳酸酯-聚酯以及其他一些共聚物。
The activation of CO2 and relevant comonomers can be promoted by using catalysts consisting of appropriate chelating polymers, suitable bimetallic combinations, and prepared by appropriate procedures. In this way, aliphatic polycarbonates, polycarbonate-polyurethanes, saturated and unsaturated polycarbonate-polyesters, as well as some other copolymers were synthesized in high yields.