Synthesis of chiral metal oxide complexes with tunable electron transition-based optical activity
Synthesis of chiral metal oxide complexes with tunable electron transition-based optical activity
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DOI：
10.1039/c3cc45960h
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发表时间：
2013-01-01
影响因子：
4.9
通讯作者：
Che, Shunai
中科院分区：
文献类型：
--
作者：
Ma, Liguo;Duan, Yingying;Che, Shunai
合成了手性金属氧化物配合物，其对圆偏振光的光学响应在整个紫外-可见吸收光谱范围内都是可调的。这种光学活性归因于在非对称电场作用下从基态到激发态的电子跃迁或从价带到导带的电子跃迁。
Chiral metal oxide complexes with tunable optical response to circularly polarised light over the full range of the UV-Vis absorption band were synthesised. This optical activity was attributed to electronic transitions from the ground state to the excited state or from the valence band to the conduction band under an asymmetric electric field.