ALKALOIDS OF ETHIOPIAN CALPURNIA-AUREA SUBSP AUREA

ALKALOIDS OF ETHIOPIAN CALPURNIA-AUREA SUBSP AUREA
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DOI:
10.1016/s0031-9422(00)81306-0
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发表时间:
1986-01-01
期刊:
影响因子:
3.8
通讯作者:
MASCAGNI, P
MASCAGNI, P
中科院分区:
生物学2区
文献类型:
--
作者:
ASRES, K;GIBBONS, WA;MASCAGNI, P

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两种新型生物碱3,4,13。-三羟氨酸和3 - β,4 - α二羟基13. alpha。- o -(2''-吡咯羰基)- lupine (calpaurine)从埃塞俄比亚Calpurnia aurea亚科的叶子中分离得到。钻进。此外,羽扇豆碱和epilupinine(均为新属),calpurmenine和calpurmenine pyrocarboxylic acid ester(先前在subsp.。林分但不属亚种。与13-羟丙氨酸、它的甲氨酸和吡咯羧酸酯(calpurnine)、virgiline和virgiline吡咯羧酸酯(virgiline pyro羧酸酯)等生物碱一起分离得到。钻进。
Two novel alkaloids 3.beta.,4.alpha.,13.alpha.-trihydroxylupanine and 3.beta.,4.alpha.-dihydroxy 13.alpha.-O-(2''-pyrrolylcarbonyl)-lupanine (calpaurine) have been isolated from the leaves of Ethiopian Calpurnia aurea subsp. aurea. In addition, lupinine and epilupinine (both new for the genus), calpurmenine and calpurmenine pyrrolecarboxylic acid ester (previously found in subsp. sylvatica but not in subsp. aurea) have been isolated together with 13-hydroxylupanine, its tiglate and pyrrolecarboxylic acid esters (calpurnine), virgiline and virgiline pyrrolecarboxylic acid ester, alkaloids which have been reported previously from subsp. aurea.