A triply interpenetrated microporous metal-organic framework for selective sorption of gas molecules
A triply interpenetrated microporous metal-organic framework for selective sorption of gas molecules
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DOI：
10.1021/ic7014034
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发表时间：
2007-10-15
影响因子：
4.6
通讯作者：
Zhou, Hong-Cai
中科院分区：
文献类型：
--
作者：
Chen, Banglin;Ma, Shengqian;Zhou, Hong-Cai
微孔金属有机骨架 Zn(ADC)(4,4'-Bpe)(0.5) 中心点 xG [1;合成并表征了具有三重互穿原始立方网的 ADC = 4,4'-偶氮苯二甲酸酯，4,4'-Bpe = 反式双（4-吡啶基）乙烯，G = 客体分子。活化的1a具有约3.4 x 3.4埃的孔隙，对H-2/N-2、H-2/CO和CO2/CH4表现出高度选择性的吸附行为。
A microporous metal-organic framework Zn(ADC)(4,4'-Bpe)(0.5)center dot xG [1; ADC = 4,4'-azobenzenedicarboxylate, 4,4'-Bpe = trans-bis(4-pyridyl)ethylene, G = guest molecules] with a triply interpenetrative primitive cubic net was synthesized and characterized. With pores of about 3.4 x 3.4 angstrom, the activated 1a exhibits highly selective sorption behavior toward H-2/N-2, H-2/CO, and CO2/CH4.