Gas chromatographic evidence for phase transitions in very compact octadecyl bonded silicas
Gas chromatographic evidence for phase transitions in very compact octadecyl bonded silicas
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非常致密的十八烷基键合二氧化硅中相变的气相色谱证据
DOI：
10.1016/s0021-9673(00)84920-1
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发表时间：
1980
影响因子：
4.1
通讯作者：
J. Serpinet
中科院分区：
文献类型：
--
作者：
D. Morel;J. Serpinet
证据已绑定的融合样的过渡，无论是单独的粘结材料或涂层后获得的复合相与十七烷的挥发性溶质的气相色谱使用非常紧凑的C8键合的二氧化硅作为固定相接近室温。这种现象可能是重要的解释经常观察到的不可再现性的材料在液相色谱中使用的属性。
Evidence has been bound for fusion-like transitions in either the bonded material alone or the composite phase obtained after coating with heptadecane upon gas chromatography of a volatile solute using very compact C8-bonded silicas as stationary phases near room temperature. Such phenomena may be important for the interpretation of the frequently observed irreproducibilities of properties of materials used in liquid chromatography.