Metal-Ligand Misfits: Facile Access to Rhenium-Oxo Corroles by Oxidative Metalation
Metal-Ligand Misfits: Facile Access to Rhenium-Oxo Corroles by Oxidative Metalation
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DOI：
10.1002/chem.201504307
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发表时间：
2016-01-11
影响因子：
4.3
通讯作者：
Ghosh, Abhik
中科院分区：
文献类型：
--
作者：
Einrem, Rune F.;Gagnon, Kevin J.;Ghosh, Abhik
除了一次偶然的合成，黑曲霉素是未知的，但作为催化剂和潜在的放射性药物有很大的兴趣。以[Re-2（CO）（10）]为催化剂，在萘烷中对meso-三芳基可罗啉进行氧化金属化反应，得到了一条简便、高产率的双（V）-羰基可罗啉的路线。所合成的配合物都可以通过单晶X-射线结构分析进行充分表征。
With the exception of a single accidental synthesis, rhenium corroles are unknown, but of great interest as catalysts and potential radiopharmaceuticals. Oxidative metalation of meso-triarylcorroles with [Re-2(CO)(10)] in refluxing decalin has provided a facile and relatively high-yielding route to rhenium(V)-oxo corroles. The complexes synthesized could all be fully characterized by single-crystal X-ray structure analyses.