Crystal Structure of [(C2H5)2(CH3)2N][Pd(dmit)2]2 at High Pressure

Crystal Structure of [(C2H5)2(CH3)2N][Pd(dmit)2]2 at High Pressure
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[(C2H5)2(CH3)2N][Pd(dmit)2]2 在高压下的晶体结构

DOI:
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发表时间:
2004
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通讯作者:
A. Kobayashi
A. Kobayashi
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文献类型:
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作者:
Y. Okano;T. Adachi;B. Narymbetov;H. Kobayashi;B. Zhou;A. Kobayashi

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对[(C 2 H 5 ) 2 (CH 3 ) 2 N][Pd(dmit) 2 ] 2 进行了高压晶体结构测定,它是一种独特的分子超导体,具有约7 kbar以上的压力诱导绝缘相。 10 kbar 下的结构分析揭示了压力诱导的阳离子排序与晶胞的加倍相结合。
The high-pressure crystal structure determination was performed on [(C 2 H 5 ) 2 (CH 3 ) 2 N][Pd(dmit) 2 ] 2 , which is a unique molecular superconductor with pressure-induced insulating phase above about 7 kbar. The structure analysis at 10 kbar revealed the pressure-induced cation ordering coupled with the doubling of the unit cell.