Thermodynamics of Mixed Electrolyte Solutions
Thermodynamics of Mixed Electrolyte Solutions
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DOI：
10.1139/v75-195
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发表时间：
1975-05
影响因子：
1.1
通讯作者：
J. Sangster;F. Lenzi
中科院分区：
文献类型：
--
作者：
J. Sangster;F. Lenzi
导出了偏离Zdanovskii规则Δ的一般热力学表达式。推导了Δ为零的条件，并给出了实例。对于非零的Δ值，它已经通过一个例子表明，在某些情况下，Δ可以通过引入经验假设来评估，例如Harned规则。简要讨论了Zdanovskii规则在McKay-Perring方程积分中的应用。
A general thermodynamic expression has been derived for the deviation Δ from Zdanovskii's rule. Conditions have been deduced under which Δ vanishes, and examples given. For nonzero values of Δ it has been shown by means of an example that Δ may be evaluated in some cases by the introduction of empirical assumptions, such as Harned's rule. The use of Zdanovskii's rule in facilitating the integration of the McKay–Perring equation has been discussed briefly.