Syntheses and Structures of d10 Coinage Metal Complexes of Electron-Accepting Phosphine Ligands Featuring a 3,3,4,4,5,5-Hexafluorocyclopentene Framework
Syntheses and Structures of d10 Coinage Metal Complexes of Electron-Accepting Phosphine Ligands Featuring a 3,3,4,4,5,5-Hexafluorocyclopentene Framework
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DOI：
10.1021/acs.inorgchem.8b01111
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发表时间：
2018-08-06
影响因子：
4.6
通讯作者：
Kubota，Toshio
中科院分区：
文献类型：
--
作者：
Agou，Tomohiro;Wada，Nao;Kubota，Toshio
合成了以3，3，4，4，5，5-六氟环戊烯为骨架的单膦或双膦配体的Cu（I）、Ag（I）和Au（I）配合物，并通过X射线衍射对其结构进行了表征。这些多氟膦的吸电子性质的实验揭示，通过紫外/维斯吸收的研究和晶体结构分析。研究了Au（I）配合物在炔水合反应中的催化应用。
Cu(I), Ag(I), and Au(I) complexes of monophosphine or bisphosphine ligands based on the 3,3,4,4,5,5-hexafluorocyclopentene skeleton were synthesized and structurally characterized by X-ray crystallographic analysis. The electron-withdrawing nature of these polyfluorinated phosphines was experimentally revealed via UV/vis absorption studies and crystal structure analysis. Successful catalytic application of the Au(I) complex for alkyne hydration reactions was investigated.