Isolation of reactive intermediates in deprotonation reactions with zinc alkyls.
Isolation of reactive intermediates in deprotonation reactions with zinc alkyls.
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DOI：
10.1039/c2cc32057f
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发表时间：
2012-04
影响因子：
4.9
通讯作者：
Victoria P. Colquhoun;C. Unkelbach;C. Strohmann
中科院分区：
文献类型：
--
作者：
Victoria P. Colquhoun;C. Unkelbach;C. Strohmann
利用单晶 X 射线衍射分析和量子化学计算，建立了金属化反应模型系统，即（叔丁基氨基）（哌啶甲基）二甲基硅烷 (1) 与 Et(2)Zn 的去质子化反应，可分离反应中间体，即加合物结构 [1·Et(2)Zn] (2)。
Using single crystal X-ray diffraction analysis and quantum chemical calculations, a model system for metalation reactions, the deprotonation of (tert-butylamino)(piperidinomethyl)dimethyl-silane (1) with Et(2)Zn, was established allowing for the isolation of a reactive intermediate, the adduct structure [1·Et(2)Zn] (2).