Contribution of particulate nitrate to airborne measurements of total reactive nitrogen
Contribution of particulate nitrate to airborne measurements of total reactive nitrogen
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DOI：
10.1029/2004jd005502
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发表时间：
2005-08
影响因子：
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通讯作者：
Y. Miyazaki;Y. Kondo;N. Takegawa;R. Weber;M. Koike;K. Kita;M. Fukuda;Y. Ma;A. Clarke;V. Kapustin;F. Flocke;A. Weinheimer;M. Zondlo;F. Eisele;D. Blake;B. Liley
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文献类型：
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作者：
Y. Miyazaki;Y. Kondo;N. Takegawa;R. Weber;M. Koike;K. Kita;M. Fukuda;Y. Ma;A. Clarke;V. Kapustin;F. Flocke;A. Weinheimer;M. Zondlo;F. Eisele;D. Blake;B. Liley
[1]2001年2月至4月，在太平洋上空的运输和化学演变（TRACE-P）实验期间，在美国航天局P-3B飞机上对西太平洋上空的形态氮、总活性氮（NOy）和颗粒NO3（粒径<1.3毫米）进行了同时测量。气相和颗粒NOy测量使用金管催化转化器。为了解释颗粒NOy，在实验室中测量了颗粒NH 4 NO3、KNO 3、NaNO 3和Ca（NO3）2的转化效率。只有NH_4NO_3表现出定量转化，其转化效率与HNO_3一样高。在飞机上测得的NO_y在0- 4km处比单个NO_y气体组分之和（P（NO_y）_i）系统地高10-30%。通过颗粒入液法测量颗粒NO3浓度
[1] Simultaneous measurements of speciated, total reactive nitrogen (NOy) and particulate NO3 (particle diameter <1.3 mm) were made on board the NASA P-3B aircraft over the western Pacific in February–April 2001 during the Transport and Chemical Evolution over the Pacific (TRACE-P) experiment. Gas-phase and particulate NOy was measured using a gold tube catalytic converter. For the interpretation of particulate NOy, conversion efficiencies of particulate NH4NO3, KNO3, NaNO3, and Ca(NO3)2 were measured in the laboratory. Only NH4NO3 showed quantitative conversion, and its conversion efficiency was as high as that for HNO3 .N Oy measured on board the aircraft was found to be systematically higher by 10–30% than the sum of the individual NOy gas components ( P (NOy)i) at 0–4 km. Particulate NO3 concentrations measured by a particle-into-liquid