Ultra-selective, ultra-clean 1D rotating-frame Overhauser effect spectroscopy.
Ultra-selective, ultra-clean 1D rotating-frame Overhauser effect spectroscopy.
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超选择性、超洁净一维旋转框架欧豪塞效应光谱。
DOI：
10.1039/d3cc00550j
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发表时间：
2023
期刊：
影响因子：
--
通讯作者：
Gates EL
中科院分区：
文献类型：
--
作者：
Gates EL
超选择性1D NMR实验- GEMSTONE-ROESY -在传统选择性方法失败的常见情况下，可以清晰，明确地分配ROE信号。它的有用性证明在分析天然产物环孢菌素和乳糖-N-二岩藻己糖I，提供详细的了解这些分子的结构和构象。
An ultra-selective 1D NMR experiment – GEMSTONE-ROESY – enables clear, unambiguous assignment of ROE signals in the not uncommon situation that traditional selective methods fail. Its usefulness is demonstrated in the analysis of the natural products cyclosporin and lacto-N-difucohexaose I, providing detailed insight into the structures and conformations of these molecules.