Thiofluorination of Carbon-Carbon Multiple Bonds Using Electrochemically Generated ArS(ArSSAr)+BF4-
Thiofluorination of Carbon-Carbon Multiple Bonds Using Electrochemically Generated ArS(ArSSAr)+BF4-
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DOI：
10.1246/cl.2009.1186
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发表时间：
2009-12-05
影响因子：
1.6
通讯作者：
Yoshida, Jun-ichi
中科院分区：
文献类型：
--
作者：
Fujie, Shunsuke;Matsumoto, Kouichi;Yoshida, Jun-ichi
烯烃和炔烃与ArSSAr在Bu4NBF4/CH2Cl2中低温阳极氧化生成并积累的ArS(ArSSAr)(+)BF4-反应，导致ArS基团和氟化物在碳-碳多重键上加成，以良好的收率得到硫代氟化化合物。
The reaction of alkenes and alkynes with ArS(ArSSAr)(+)BF4-, which was generated and accumulated by the low-temperature anodic oxidation of ArSSAr in Bu4NBF4/CH2Cl2, led to the addition of an ArS group and fluoride across the carbon-carbon multiple bond to give thio-fluorinated compounds in good yields.