Plant oils: The perfect renewable resource for polymer science?!
Plant oils: The perfect renewable resource for polymer science?!
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DOI：
10.1016/j.eurpolymj.2010.11.020
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发表时间：
2011-05-01
影响因子：
6
通讯作者：
Meier, Michael A. R.
中科院分区：
文献类型：
--
作者：
de Espinosa, Lucas Montero;Meier, Michael A. R.
长期以来，植物油及其衍生物由于其可再生性、全球范围内的可获得性、相对较低的价格以及丰富的应用前景，已经被聚合物化学家所使用。虽然已经使用了许多不同的合成方法，但最近的例子指向催化转化和其他有效反应的方向，以实现利用这些可再生资源更可持续地生产聚合物。在这种背景下，烯烃歧化、硫醇-烯加成和其他工艺不仅有助于更有效地合成植物油聚合物，而且还可以拓宽植物油的应用前景。这篇专题文章概述了目前的情况，并特别注意了烯烃歧化和硫醇-烯化学作为合成方法和聚合技术的使用。(C)2010爱思唯尔有限公司。保留所有权利。
Already for a long time, plant oils and their derivatives have been used by polymer chemists due to their renewable nature, world wide availability, relatively low price, and their rich application possibilities. Although many different synthetic approaches have been used, more recent examples are pointing in the direction of catalytic transformations and other efficient reactions to achieve a more sustainable production of polymers from these renewable resources. In this context, olefin metathesis, thiol-ene additions, and other processes can contribute not only to a more efficient synthesis of plant oil based polymers, but also to broaden the application possibilities of plant oils. This feature article provides an overview of the present situation with special attention to the use of olefin metathesis and thiol-ene chemistry as synthetic methods and as polymerization techniques. (C) 2010 Elsevier Ltd. All rights reserved.